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Advanced Degradation of Lignin from Palm Oil Mill Effluent (POME) by a Combination of Photocatalytic-Fenton Treatment and TiO 2 Nanoparticle as the Catalyst
Water, Air, & Soil Pollution ( IF 2.9 ) Pub Date : 2020-05-23 , DOI: 10.1007/s11270-020-04617-8
Osi Arutanti , Ajeng Arum Sari , Anita Berkah , Muhammad Nurdin , Muhammad Arifuddin Fitriady , Yusnita Parmawati , Nino Rinaldi , Adhi Yuniarto , Tony Hadibarata

Lignin-based black liquor from oil palm empty fruit bunches (OPEFB) as a side product of the pretreatment process in second-generation bioethanol is the next problem in developing renewable energy. Therefore, developing technology to overcome this problem is needed. In this study, titanium dioxide (TiO2) as photocatalyst and their synergy with heterogeneous Fenton-like process for degrading lignin was investigated. Several conditions were varied and investigated independently to obtain the optimum condition. Result showed that among the conditions has the optimum number. 0.5 g of FeSO4, 400 mg/L of H2O2, pH 4, and 0.03 g of TiO2 were the optimum condition of heterogeneous photo-Fenton to decompose 100 ppm of Lignin up to 90% under UV-A irradiation. Post annealing treatment of the prepared TiO2 improved the photodegradation around 50%. The schematic illustration of lignin photodecomposition also supported the results.



中文翻译:

光催化芬顿处理和TiO 2纳米粒子联合催化从棕榈油厂废水(POME)中深度降解木质素

来自油棕空果串(OPEFB)的木质素黑液作为第二代生物乙醇预处理工艺的副产品,是开发可再生能源中的下一个问题。因此,需要开发克服该问题的技术。在这项研究中,研究了二氧化钛(TiO 2)作为光催化剂及其与非均相Fenton样工艺降解木质素的协同作用。改变几个条件并独立研究以获得最佳条件。结果表明,在该条件下具有最佳数量。0.5克的FeSO的4,400毫克/ H L 2 ö 2,pH为4,并0.03克的TiO 2是非均质光芬顿在UV-A辐射下分解100 ppm木质素达90%的最佳条件。所制备的TiO 2的后退火处理将光降解提高了约50%。木质素光分解的示意图也支持该结果。

更新日期:2020-05-23
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