The integration of biocatalysis with chemocatalysis combines the excellent selectivity of the former with the robust reactivity of the latter and offers many advantages, such as lower cost, higher yield, enhanced selectivity, as well as less waste generation. In spite of the challenge of incompatibilities between different classes of catalysts, recent advances in synthetic chemistry and biology provide ample opportunities for multistep cascade transformations that combine biocatalysis and chemocatalysis. Herein, we review recent progress in merging biocatalysis with chemocatalysis, highlighting selected examples of photo-/electricity-driven biotransformations and recently developed strategies for addressing the catalyst incompatibility issue.

中文翻译：

---

将生物催化与化学催化相结合以进行选择性转化。

生物催化与化学催化的整合将前者的出色选择性与后者的强大反应性结合在一起，并提供了许多优势，例如成本更低，产量更高，选择性更高以及废物产生更少。尽管面临不同类别催化剂之间不兼容的挑战，但合成化学和生物学的最新进展为结合生物催化和化学催化的多步级联转化提供了充足的机会。本文中，我们回顾了将生物催化与化学催化相结合的最新进展，重点介绍了光/电驱动生物转化的精选实例，以及解决了催化剂不相容性问题的最新开发策略。