当前位置: X-MOL 学术Synthesis › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Synthesis of Oxazoline and Oxazole Derivatives by Hypervalent-Iodine-Mediated Oxidative Cycloaddition Reactions
Synthesis ( IF 2.6 ) Pub Date : 2020-05-18 , DOI: 10.1055/s-0040-1707122
Akira Yoshimura 1 , Akio Saito 2 , Viktor V. Zhdankin 1 , Mekhman S. Yusubov 3
Affiliation  

Organohypervalent iodine reagents are widely used for the preparation of various oxazolines, oxazoles, isoxazolines, and isoxazoles. In the formation of these heterocyclic compounds, hypervalent iodine species can serve as the activating reagents for various substrates, as well as the heteroatom donor reagents. In recent research, both chemical and electrochemical approaches toward generation of hypervalent iodine species have been utilized. The in situ generated active species can react with appropriate substrates to give the corresponding heterocyclic products. In this short review, we summarize the hypervalent-iodine­-mediated preparation of oxazolines, oxazoles, isoxazolines, and isoxazoles starting from various substrates.

中文翻译:

高价碘介导的氧化环加成反应合成恶唑啉和恶唑衍生物

有机高价碘试剂被广泛用于制备各种恶唑啉,恶唑,异恶唑啉和异恶唑。在这些杂环化合物的形成中,高价碘物质可以用作各种底物的活化剂,以及杂原子供体试剂。在最近的研究中,已经利用化学和电化学方法来产生高价碘物质。原位产生的活性物质可以与合适的底物反应,得到相应的杂环产物。在这篇简短的综述中,我们总结了从各种底物开始的高价碘介导的恶唑啉,恶唑,异恶唑啉和异恶唑的制备。
更新日期:2020-05-18
down
wechat
bug