Tertiary enamides display versatile reactivity and great stability compared to their enamine congeners. This review covers progress made in the development of new methods involving the enaminic reactivity of tertiary enamides with respect to the synthesis of complex nitrogen-containing compounds. A focus on the preparation of biologically active molecules is also presented. The syntheses reported herein are classified based on their reaction type. In addition, mechanistic insights are given for most of the new transformations.

中文翻译：

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叔酰胺作为多种多样的有价值的底物，可达到化学多样性

与它们的烯胺同类物相比，叔酰胺显示出广泛的反应性和出色的稳定性。这篇综述涵盖了在开发复杂的含氮化合物方面涉及叔酰胺的烯胺反应性的新方法方面的进展。还提出了对生物活性分子制备的关注。本文报道的合成基于其反应类型进行分类。此外，对大多数新的转换都提供了机械方面的见解。