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Hydrosulfide complexes of the transition elements: diverse roles in bioinorganic, cluster, coordination, and organometallic chemistry.
Chemical Society Reviews ( IF 46.2 ) Pub Date : 2020-05-18 , DOI: 10.1039/c9cs00570f
Michael D Pluth 1 , Zachary J Tonzetich
Affiliation  

Sulfur-based ligands are versatile donors that play important roles in a wide array of subdisciplines of inorganic chemistry including organometallic chemistry, bioinorganic chemistry, and cluster science. Despite the breadth of compounds containing sulfur-based ligands, those containing the simplest mercapto group, hydrosulfide ion (HS), are significantly less developed. The acceptance of H2S/HS as important biological signaling compounds during the last decade has engendered a renewed interest in the chemistry of these species. Bioinorganic reactivity of hydrosulfide, however, is only one aspect of its fascinating chemistry, much of which revolves around its interactions with transition metal ions. The coordination of HS to d-block elements produces a unique class of substances that differ in significant ways from more ubiquitous metal thiolates. This review examines the preparation, structure, spectroscopy, and reactivity of such compounds and the roles they play across several fields of chemistry.

中文翻译:

过渡元素的氢硫化物络合物:在生物无机,团簇,配位和有机金属化学中的多种作用。

基于硫的配体是多用途的供体,在无机化学的各个子学科(包括有机金属化学,生物无机化学和团簇科学)中发挥重要作用。尽管含有硫系配体的化合物的广度,那些含有最简单的巯基,氢硫化物离子(HS - ),被显著欠发达。H的验收2 S / HS -在过去十年中作为重要的生物化合物的信令已经在主义及其这些物质的化学性质的新的兴趣。然而,氢硫化物的生物无机反应性只是其令人着迷的化学反应的一个方面,其中大部分围绕着它与过渡金属离子的相互作用而发生。HS的协调-d-嵌段元素产生独特的一类物质,其与更普遍存在的金属硫醇盐有很大不同。本文综述了这类化合物的制备,结构,光谱学和反应性,以及它们在化学的几个领域中所扮演的角色。
更新日期:2020-06-22
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