当前位置: X-MOL 学术Acta Cryst. C › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Chimeric supramolecular synthons in Ph2Te2(I2)Se.
Acta Crystallographica Section C ( IF 0.8 ) Pub Date : 2020-05-18 , DOI: 10.1107/s2053229620006166
Yury V Torubaev 1
Affiliation  

Iodination of Ph2Te2Se by molecular iodine is directed towards the Te atom and yields {diiodo[(phenyltellanyl)selanyl]‐λ4‐tellanyl}benzene, PhTeSeTeI2Ph or C12H10I2SeTe2. The molecule can be considered as a chimera of PhTeSeR, PhTeSeTePh and R′TeI2Ph fragments. The crystal structure features a complex interplay of the supramolecular synthons Te…π(Ph), Se…Te and I…Te, combining molecules into a three‐dimensional framework. Their combination affords long‐range supramolecular synthons which are fused in a way resembling the mythological chimera and could be defined as chimeric supramolecular synthons. The energies of the intermolecular interactions have also been calculated and analyzed.

中文翻译:

Ph2Te2(I2)Se中的嵌合超分子合成子。

的Ph碘化22硒通过分子碘朝向碲原子和产量{二碘·〔(phenyltellanyl)selanyl]-λ 4 -tellanyl}苯,PhTeSeTeI 2博士或C 12 ħ 102塞特2。该分子可被认为是PhTeSe的嵌合体[R,PhTeSeTePh和- [R '的Tel 2酸碱度碎片。晶体结构具有超分子合成子Te…π(Ph),Se…Te和I…Te的复杂相互作用,将分子组合成三维框架。它们的结合提供了远距离超分子合成子,其融合方式类似于神话般的嵌合体,可被定义为嵌合的超分子合成子。分子间相互作用的能量也已被计算和分析。
更新日期:2020-05-18
down
wechat
bug