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Phase Structure, Microstructure, and Magnetic Properties of (Nd-Ce) 13.4 Fe 79.9 B 6.7 Alloys
Journal of Superconductivity and Novel Magnetism ( IF 1.8 ) Pub Date : 2020-05-15 , DOI: 10.1007/s10948-020-05537-8
M. H. Rong , G. Fu , Q. R. Yao , J. Wang , G. H. Rao , H. Y. Zhou , Z. P. Jin

Phase structure and microstructure of (Nd1-xCex)13.4Fe79.9B6.7 (x = 0.0–1.0) alloys that were prepared via the arc-melting method were studied experimentally in this work. The results reveal that (Nd1-xCex)13.4Fe79.9B6.7 alloys annealed at 1173 K for 360 h are a single (NdCe)2Fe14B phase with the tetragonal Nd2Fe14B-typed structure (space group P42/mnm). The formation of continuous (NdCe)2Fe14B solid solution phase in annealed (Nd1-xCex)13.4Fe79.9B6.7 alloys was confirmed. On the other hand, magnetic measurements exhibit that the coercivity, remanence, maximum magnetic energy product, and Curie temperature of (Nd1-xCex)13.4Fe79.9B6.7 ribbons that were fabricated by melt spinning technology decrease gradually with increasing Ce content, which results from the substitution of Nd by Ce in Nd2Fe14B phase due to inferior intrinsic magnetic properties of Ce2Fe14B phase.

中文翻译:

(Nd-Ce)13.4 Fe 79.9 B 6.7合金的相结构,显微组织和磁性

 在这项工作中,通过实验研究了通过电弧熔化法制备的(Nd 1-x Ce x13.4 Fe 79.9 B 6.7x = 0.0-1.0)合金的相结构和微观结构。结果表明,在1173 K退火360 h的(Nd 1-x Ce x13.4 Fe 79.9 B 6.7合金为单一(NdCe)2 Fe 14 B相,具有四方Nd 2 Fe 14 B型结构(空间群) P4 2 / mnm)。连续(NdCe)2 Fe的形成确认了在退火(Nd 1-x Ce x13.4 Fe 79.9 B 6.7合金中的14 B固溶体相。另一方面,磁性测量表明,通过熔融纺丝技术制备的(Nd 1-x Ce x13.4 Fe 79.9 B 6.7薄带的矫顽力,剩磁,最大磁能积和居里温度随Ce含量的增加而逐渐降低,这是由于Ce 2 Fe 14的固有磁性能较差而在Nd 2 Fe 14 B相中用Ce替代了Nd所致B相。
更新日期:2020-05-15
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