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Cobalt-Catalyzed Ligand-Controlled Divergent Regioselective Reactions of 1,6-Enynes with Thiols
Organometallics ( IF 2.8 ) Pub Date : 2020-05-15 , DOI: 10.1021/acs.organomet.0c00179
Gaowei Wang 1 , Ruhima Khan 1 , Haojie Liu 1 , Guoli Shen 1 , Fan Yang 1 , Jingchao Chen 1 , Yongyun Zhou 1, 2 , Baomin Fan 1, 2
Affiliation  

An efficient cobalt-catalyzed method for the synthesis of carbocyclic organosulfur compounds from 1,6-enynes and thiols has been developed. The significance of this methodology is the ability to give three different cyclization products depending on the ligands used. The products were obtained in moderate to good yields with broad substrate scope.

中文翻译:

1,6-烯炔与硫醇的钴催化配体控制的发散区域选择性反应

已经开发了一种有效的钴催化方法,用于从1,6-烯和硫醇合成碳环有机硫化合物。该方法的重要性在于能够根据所使用的配体产生三种不同的环化产物。以中等至良好的产率获得产物,并具有广泛的底物范围。
更新日期:2020-05-15
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