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Hydrogen generation via the reaction of an activated aluminum slurry with water
International Journal of Hydrogen Energy ( IF 7.2 ) Pub Date : 2020-05-15 , DOI: 10.1016/j.ijhydene.2020.04.161
Jason Fischman , Peter Godart , Douglas Hart

Presented here is the formulation and characterization of a stable aluminum slurry fuel that reacts readily and exothermically with liquid water to produce hydrogen gas and AlOOH (boehmite). Bulk pure aluminum is first surface-treated with a gallium-indium eutectic, then ground into a powder and suspended in mineral oil containing 4–8 wt% fumed silica as a shear-thinning agent. Aluminum mass fractions of up to 65 wt% are shown here. This formulation results in a slurry fuel that can be pumped continuously at low power while remaining in suspension for over 2 months. The fuel is also shown here to exhibit a high degree of reaction completion (93.4%) with a total measured energy density of 28.7 MJ/L and specific energy of 17.5 MJ/kg. Finally, to show the feasibility of using this fuel for on-demand hydrogen production in a representative power system, a prototype continuous-flow reactor was developed, and validation experiments were performed, the results of which are presented here.



中文翻译:

通过活性铝浆与水反应生成氢

此处介绍的是稳定的铝浆燃料的配方和特性,该燃料容易与放热反应并与液态水反应生成氢气和AlOOH(勃姆石)。散装的纯铝首先用镓铟共晶表面处理,然后研磨成粉末,然后悬浮在含有4-8 wt%气相二氧化硅作为剪切稀化剂的矿物油中。此处显示的铝质量分数高达65 wt%。该配方产生的浆状燃料可以在低功率下连续泵送,同时保持悬浮状态超过2个月。此处还显示该燃料表现出高度的反应完成率(93.4%),总测量能量密度为28.7 MJ / L,比能量为17.5 MJ / kg。最后,

更新日期:2020-06-30
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