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A review of the current analytical approaches for evaluating, compensating and exploiting self-absorption in Laser Induced Breakdown Spectroscopy
Spectrochimica Acta Part B: Atomic Spectroscopy ( IF 3.3 ) Pub Date : 2020-07-01 , DOI: 10.1016/j.sab.2020.105878
Fatemeh Rezaei , Gabriele Cristoforetti , Elisabetta Tognoni , Stefano Legnaioli , Vincenzo Palleschi , Ali Safi

Abstract In this paper a review of different approaches for handling the self-absorption effect in Laser-Induced Breakdown Spectroscopy (LIBS) applications is presented. From an analytical point of view, self-absorption is a major issue affecting the accuracy of LIBS quantitative analysis. Self-absorption impacts emission line profiles and intensities, resulting in non-linear calibration curves and influencing the estimation of the sample composition. The main purpose of this work is presenting a summary of the experimental parameters giving raise to self-absorption and a thorough study of the different strategies for its estimation, compensation and exploitation in order to improve the analytical accuracy of the LIBS technique.

中文翻译:

评估、补偿和利用激光诱导击穿光谱自吸收的当前分析方法综述

摘要 本文综述了在激光诱导击穿光谱 (LIBS) 应用中处理自吸收效应的不同方法。从分析的角度来看,自吸收是影响LIBS定量分析准确性的主要问题。自吸收影响发射线轮廓和强度,导致非线性校准曲线并影响样品成分的估计。这项工作的主要目的是总结引起自吸收的实验参数,并对其估计、补偿和利用的不同策略进行深入研究,以提高 LIBS 技术的分析精度。
更新日期:2020-07-01
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