The Fujiwara–Moritani reaction between p-methylacetanilide and n-butyl acrylate, catalysed by Pd(OAc)₂ in the presence of toluenesulfonic acid and benzoquinone, was (re-)investigated using reaction calorimetry and complementary spectroscopic methods. The (most) active catalyst was identified and the catalytic turnover rate was found to be independent of all stoichiometric reagents. Catalyst regeneration and deactivation pathways are discussed.

中文翻译：

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再次探讨藤原-森谷反应的机理

使用反应量热法和互补光谱法对（甲基）对甲氧基苯甲酸与丙烯酸正丁酯之间的Fujiwara-Moritani反应进行了（重新）研究，该反应在甲苯磺酸和苯醌存在下被Pd（OAc）₂催化。鉴定了（最）活性催化剂，发现催化转换速率与所有化学计量试剂无关。讨论了催化剂的再生和失活途径。