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Conjugated porous polymers: incredibly versatile materials with far-reaching applications.
Chemical Society Reviews ( IF 46.2 ) Pub Date : 2020-05-13 , DOI: 10.1039/c9cs00315k
Dominic Taylor 1 , Scott J Dalgarno , Zhengtao Xu , Filipe Vilela
Affiliation  

Conjugated porous polymers (CPPs) are a class of amorphous polymer networks that are, in their design, fully cross-linked and fully π-conjugated. The cross-linked nature of CPPs means that they have permanent intrinsic porosity (on the nanometer scale), which, in combination with the fully π-conjugated framework, makes these materials unique among the wider class of porous polymeric materials. In recent years, the need for new and efficient functional materials has driven the development of CPPs as versatile platforms for applications including (photo)catalysis, light harvesting, gas separation and storage, chemosensing, environmental remediation and energy storage. The efficiency of these materials towards these described applications is heavily influenced by the choice of molecular building blocks and synthetic conditions, allowing for facile tailoring and optimisation of the structure and properties. The aim of this review is to highlight select works on CPPs, including basic structural design principles, various synthetic protocols and topical applications of these versatile materials.

中文翻译:

共轭多孔聚合物:用途广泛的用途广泛的材料。

共轭多孔聚合物(CPP)是一类无定形聚合物网络,在其设计中是完全交联且完全π共轭的。CPP的交联性质意味着它们具有永久的固有孔隙率(纳米级),这与完全π共轭的骨架相结合,使这些材料在更广泛的多孔聚合物材料类别中独树一帜。近年来,对新型高效功能材料的需求推动了CPP作为多功能平台的发展,这些平台的应用包括(光)催化,光收集,气体分离和存储,化学传感,环境修复和能量存储。这些材料在上述应用中的效率在很大程度上受到分子构件的选择和合成条件的影响,允许轻松进行剪裁以及结构和属性的优化。这篇综述的目的是强调有关CPP的精选作品,包括基本结构设计原理,各种合成规程以及这些通用材料的局部应用。
更新日期:2020-06-22
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