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Regioselective Synthesis of Unsymmetrical 3-(Quinolin-3-yl)Pentane-1,5-Diones in the Aqueous Medium through Montmorillonite KSF Catalysis
Polycyclic Aromatic Compounds ( IF 2.4 ) Pub Date : 2020-05-03 , DOI: 10.1080/10406638.2020.1760324
Eethamukkala Ubba 1 , Fazlur-Rahman Nawaz Khan 1
Affiliation  

Abstract

In the presence of heterogeneous catalyst Montmorillonite KSF (M-KSF) 2-chloro-3-formyl quinolines, 1 were successfully converted into regioselective 3-(quinolin-3-yl)pentane-1,5-diones, 3. A one-pot sequential reaction (aldol-condensation-Michael addition) of distinct acetophenones, 2 was efficient in an aqueous medium.



中文翻译:

蒙脱石KSF催化在水介质中区域选择性合成不对称3-(Quinolin-3-yl)Pentane-1,5-二酮

摘要

在多相催化剂蒙脱石 KSF (M-KSF) 2-chloro-3-formyl quinolines 的存在下,1成功地转化为区域选择性的 3-(quinolin-3-yl)pentane-1,5-diones, 3。不同苯乙酮的一锅顺序反应(醛醇缩合-迈克尔加成)2在水性介质中是有效的。

更新日期:2020-05-03
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