ABSTRACT Thieno-fused subporphyrazines (TPs) containing a central and axially substituted boron atom are a class of compounds with interesting optical and redox properties. Here we present our efforts towards expanding this class of compounds using various thiophene substrates that were prepared by cyanation or nitration of 3,4-dibromothiophene. Moreover, we show that one TP derivative forms a 2:1 complex in the solid state with C70. GRAPHICAL ABSTRACT

中文翻译：

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通过功能化噻吩前体开发新型噻吩并四氮杂卟啉

摘要含有中心和轴向取代的硼原子的噻吩并稠合亚卟啉 (TP) 是一类具有有趣的光学和氧化还原特性的化合物。在这里，我们展示了我们使用通过氰化或硝化 3,4-二溴噻吩制备的各种噻吩底物来扩展此类化合物的努力。此外，我们表明一种 TP 衍生物在固态下与 C70 形成 2:1 的复合物。图形概要