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A new mechanism for selective recognition of cyanide in organic and aqueous solution
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2020-05-11 , DOI: 10.1002/ejoc.202000342
Ergin Keleş 1 , Burcu Aydıner 1 , Yahya Nural 2, 3 , Nurgül Seferoğlu 4 , Ertan Şahin 5 , Zeynel Seferoğlu 1
Affiliation  

We report that 3,5‐dinitro‐(N‐phenyl)benzamide is proposed as a simple colorimetric and fluorimetric chemosensor for selective determination of cyanide anion in organic and aqueous solutions via novel chemodosimeter approach named as nucleophilic aromatic substitution of hydrogen (NASH). Moreover, novel biological important benzisoxazole derivative has been synthesized with cyanide‐induced ring closing mechanism.
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中文翻译:

一种选择性识别有机和水溶液中氰化物的新机制

我们报道了3,5-二硝基-(N-苯基)苯甲酰胺被提议作为一种简单的比色和荧光化学传感器,用于通过新颖的化学计量计方法称为氢的亲核芳香族取代(NASH)选择性测定有机和水溶液中的氰化物阴离子。此外,已经合成了具有氰化物诱导的闭环机理的新型重要的生物重要苯并异恶唑衍生物。
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更新日期:2020-05-11
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