This work laid emphasis on catalytic pyrolysis of Styrax japonicus to construct a biomass-to-energy conversion platform. CO₂ was particularly chosen to enhance the catalytic pyrolysis of the biomass waste, in reference to N₂-purged pyrolysis. The specific roles of CO₂ on pyrolysis of S. japonicus in line with synergistic effect of Ni-based catalysts was investigated. It was shown that CO₂ played as an oxidant for CO formation via homogeneous gas phase reaction of CO₂ with volatile organic carbons (VOCs) liberated from the thermolysis of S. japonicus. Ni/SiO₂ catalyst expedited dehydrogenation (DH) of the VOCs, resulting in significant H₂ generation and alteration of aromaticity in VOCs. Each CO₂ and Ni catalyst independently enhanced CO and H₂ formation, respectively, and their synergistic effects were shown at ≥ 600 °C. Coke deposition on the Ni/SiO₂ catalyst was confirmed after catalytic pyrolysis, while the suppression of coke formation on the catalyst surface was achieved under the CO₂ environment.

这项工作侧重于日本菊（Styrax japonicus）的催化热解，以构建生物质-能量转化平台。相对于N ₂净化的热解，特别地选择CO ₂以增强生物质废物的催化热解。CO的特定角色₂上的热解S.刺参与Ni基催化剂的协同作用线进行了研究。结果表明，CO ₂通过CO ₂与日本血吸虫热解所释放的挥发性有机碳（VOC）的均相气相反应，作为CO形成的氧化剂。镍/二氧化硅₂催化剂加速了VOC的脱氢（DH），导致显着的H ₂生成和VOC中芳香性的改变。每种CO ₂和Ni催化剂分别独立地增强了CO和H _2的形成，并且在≥600°C下显示了它们的协同作用。催化热解后，证实了焦炭沉积在Ni / SiO ₂催化剂上，而在CO ₂环境下，抑制了焦炭在催化剂表面的形成。