Owing to the superiority of high-power density and excellent cycling stability, supercapacitors (SCs) have been expected to substitute for secondary batteries as the desired orientation selected for energy storage devices. The incorporation of various heteroatoms into carbon-based materials via surface functionalization or doping technique has been considered as a significant way to ameliorate its properties for SCs application. In this review, a wide variety of fluorine-doped/fluorinated carbon-based materials are put together to overview the development path, preparation route and areas of application in detail. We critically review the optimization effect in electrochemical performance induced by the participation of fluorine element. Moreover, compared with large-scale energy storage devices, miniaturization, flexibility and planarization are an emerging development tendency of SCs. Fluorine-doped/fluorinated carbon-based materials hold great promise in the future.

由于高功率密度和出色的循环稳定性的优越性，人们期望超级电容器（SC）可以替代二次电池，作为为储能设备选择的理想方向。通过表面功能化或掺杂技术将各种杂原子掺入碳基材料中已被认为是改善其在SCs应用中的性能的重要途径。在这篇综述中，各种各样的氟掺杂/氟化碳基材料被放在一起，以详细概述其发展路径，制备途径和应用领域。我们批判性地回顾了氟元素的参与对电化学性能的优化作用。而且，与大型储能装置相比，小型化，柔性和平面化是SC的新兴发展趋势。掺氟/氟化碳基材料在未来具有广阔的前景。