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Infusing High-density Polyethylene with Graphene-Zinc Oxide to Produce Antibacterial Nanocomposites with Improved Properties
Chinese Journal of Polymer Science ( IF 4.3 ) Pub Date : 2020-05-09 , DOI: 10.1007/s10118-020-2392-z
You-Li Yao , Manuel Reyes De Guzman , Hong Duan , Chen Gao , Xu Lin , Yi-Hua Wen , Juan Du , Li Lin , Jui-Chin Chen , Chin-San Wu , Maw-Cherng Suen , Ya-Li Sun , Wei-Song Hung , Chi-Hui Tsou

Nanocomposites of high-density polyethylene (HDPE) modified with 0.2 phr graphene-zinc oxide (GN-ZnO) exhibited optimal mechanical properties and thermal stability. Two other nano-materials—GN and nano-ZnO—were also used to compare them with GN-ZnO. Increasing the content of GN-ZnO gradually enhanced the antibacterial and barrier properties, but the addition of 0.3 phr GN-ZnO led to agglomeration that caused defects in the nanocomposites. Herein, we investigated the antibacterial and barrier properties of HDPE nanocomposites infused with different nanoparticles (GN, ZnO, GN-ZnO) of varying concentrations. HDPE and the nanoparticles were melt-blended together in a Haake-Buchler Rheomixer to produce a new environment-friendly nano-material with improved physical and chemical properties. The following characterizations were conducted: tensile test, thermogravimetric analysis, morphology, differential scanning calorimetry, X-ray diffraction, antibacterial test, and oxygen and water vapor permeation test. The results showed that the crystallinity of HDPE was affected with the addition of GN-ZnO, and the nanocomposites had effective antibacterial capacity, strong mechanical properties, high thermal stability, and excellent barrier performance. This type of HDPE nanocomposites reinforced with GN-ZnO would be attractive for packaging industries.



中文翻译:

向石墨烯-氧化锌中注入高密度聚乙烯以生产性能得到改善的抗菌纳米复合材料

用0.2 phr石墨烯-氧化锌(GN-ZnO)改性的高密度聚乙烯(HDPE)纳米复合材料表现出最佳的机械性能和热稳定性。还使用了另外两种纳米材料GN和纳米ZnO将它们与GN-ZnO进行了比较。GN-ZnO含量的增加逐渐增强了抗菌和阻隔性能,但添加0.3 phr GN-ZnO导致团聚,从而导致纳米复合材料的缺陷。在这里,我们研究了注入不同浓度的不同纳米颗粒(GN,ZnO,GN-ZnO)的HDPE纳米复合材料的抗菌和阻隔性能。HDPE和纳米颗粒在Haake-Buchler Rheomixer中熔融共混在一起,生产出一种具有改善的物理和化学特性的新型环保纳米材料。进行了以下表征:拉伸试验,热重分析,形态,差示扫描量热法,X射线衍射,抗菌测试以及氧气和水蒸气渗透测试。结果表明,加入GN-ZnO会影响HDPE的结晶度,且纳米复合材料具有有效的抗菌能力,较强的机械性能,较高的热稳定性和优异的阻隔性能。这种用GN-ZnO增强的HDPE纳米复合材料将对包装行业具有吸引力。高热稳定性和出色的阻隔性能。这种用GN-ZnO增强的HDPE纳米复合材料将对包装行业具有吸引力。高热稳定性和出色的阻隔性能。这种用GN-ZnO增强的HDPE纳米复合材料将对包装行业具有吸引力。

更新日期:2020-05-09
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