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Visible Light Driven Copper(I) Catalyzed Oxyamination of Electron Deficient Alkenes†
Chinese Journal of Chemistry ( IF 5.4 ) Pub Date : 2020-05-09 , DOI: 10.1002/cjoc.202000105
Sanliang Li 1 , Qiaoyu Chen 1 , Wenbo Li 2 , Guangxin Gu 3 , Junliang Zhang 1
Affiliation  

A visible light driven Cu(I)‐catalyzed intermolecular oxyamination of electron‐deficient olefins has been achieved by using O‐benzoylhydroxylamines as donors both for amine and oxygen. The transformation properties afford mild conditions and a wide substrate scope, providing access to ester derivatives of β‐amino alcohols with good yields and high regioselectivity.

中文翻译:

可见光驱动的铜(I)催化电子不足的烯烃的氧化作用†

通过使用O-苯甲酰基羟胺作为胺和氧的供体,实现了可见光驱动的Cu(I)催化的缺电子烯烃的分子间氧化。转化性质提供了温和的条件和广泛的底物范围,使人们能够以高收率和高区域选择性获得β-氨基醇的酯衍生物。
更新日期:2020-05-09
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