当前位置: X-MOL 学术Solid State Ionics › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
The effect of LiAlSiO4 additions on lithium ionic conductivity of garnet Li6.75La3Zr1.75Nb0.25O12 prepared by solid-state synthesis
Solid State Ionics ( IF 3.2 ) Pub Date : 2020-05-07 , DOI: 10.1016/j.ssi.2020.115313
Wenjuan Xue , Qiaoling Yang , Sha Li , Yuping Liu , Lian Wang , Renju Cheng , Changguo Chen

LiAlSiO4 (LAS) was added to Li6.75La3Zr1.75Nb0.25O12 (LLZNO) to improve its lithium ionic conductivity for the first time. After the addition of 1 wt% LAS, the lithium ionic conductivity of LLZNO increased from 1.21 × 10−4 S cm−1 to 6.93 × 10−4 S cm−1 at room temperature (25 °C). The relative density also increased from 80% to 94% and the critical current density (CCD) has been improved. Scanning electron microscopy (SEM) and electrochemical impedance spectroscopy (EIS) results showed that the addition of LAS improved the grains connectivity and reduced the grain boundary resistance, which increased Li+ movement between grains.



中文翻译:

固相合成制备LiAlSiO 4对石榴石Li 6.75 La 3 Zr 1.75 Nb 0.25 O 12锂离子电导率的影响

LiAlSiO 4(LAS)被首次添加到Li 6.75 La 3 Zr 1.75 Nb 0.25 O 12(LLZNO)中以提高其锂离子电导率。添加1 wt%的LAS之后,LLZNO的锂离子电导率从1.21×10 -4  S cm -1增加到6.93×10 -4  S cm -1在室温(25°C)下。相对密度也从80%增加到94%,并且临界电流密度(CCD)得到了改善。扫描电子显微镜(SEM)和电化学阻抗谱(EIS)结果表明,添加LAS可以改善晶粒的连通性并降低晶界电阻,从而增加晶粒间的Li +运动。

更新日期:2020-05-07
down
wechat
bug