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Design of practical Ce/CoMnAl-LDO catalyst for low-temperature NH3-SCR
Catalysis Communications ( IF 3.7 ) Pub Date : 2020-05-06 , DOI: 10.1016/j.catcom.2020.106037
Xinyu Zhang , Qinghua Yan , Qiang Wang

A highly active Ce/CoMnAl-LDO catalyst for low-temperature NH3-SCR with good thermal stability and SO2/H2O resistance was designed from layered double hydroxides (LDHs). At 100–250 °C, Ce0.5/Co1Mn0.5Al0.5Ox-LDO showed practically ~100% NOx conversion compared to Ce-Co-Mn/γ-Al2O3 (63.4–90.3%) of the same metal composition prepared by the common wet-impregnation method. The LDO catalytic material showed very stable NOx conversion of 83.3% at 200 °C after 10 h test with 100 ppm SO2 in the feed stream, superior performance when compared to the control catalysts Co1Mn0.5Al0.5Ox (60.2%) and Ce-Co-Mn/γ-Al2O3 (28%). The thermal stability and resistance to water vapor were also investigated. Various studies suggested that the excellent performance of Ce0.5/Co1Mn0.5Al0.5Ox-LDO can be attributed to the high dispersion of active metal species, large specific surface area, moderate redox capacity and strong acidity.



中文翻译:

低温NH 3 -SCR实用Ce / CoMnAlAl-LDO催化剂的设计。

由层状双氢氧化物(LDHs)设计了一种用于低温NH 3 -SCR的高活性Ce / CoMnAlAl-LDO催化剂,具有良好的热稳定性和耐SO 2 / H 2 O性能。在100-250℃下,CE 0.5 / Co的1的Mn 0.5的Al 0.5 ø X -LDO表明几乎〜100%NO X转化率相比的Ce-Co-Mn的/γ-Al系2 Ö 3的(63.4-90.3%)用普通的湿法浸渍法制得的金属成分相同。该LDO催化材料显示出非常稳定的NO X的83.3%的转化率在H检验200℃后10℃用100ppm SO 2进料流中,性能优越当与对照相比,催化剂钴1的Mn 0.5的Al 0.5 ø X(60.2%)和Ce-Co-Mn的/γ-Al系2 ö 3(28%)。还研究了热稳定性和耐水蒸气性。各种研究表明,Ce 0.5 / Co 1 Mn 0.5 Al 0.5 O x -LDO的优异性能可归因于活性金属种类的高分散性,大的比表面积,适度的氧化还原能力和强酸性。

更新日期:2020-05-06
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