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Hierarchical chirality expression of gemini surfactant aggregates via equilibrium between chiral nucleotide and nonchiral mono-anions.
Chirality ( IF 2 ) Pub Date : 2020-04-28 , DOI: 10.1002/chir.23230
Dmytro Dedovets 1, 2 , Barbara Martin 1 , Yutaka Okazaki 1, 3 , Thierry Buffeteau 4 , Emilie Pouget 1 , Reiko Oda 1
Affiliation  

The assembling behaviors of nonchiral dicationic amphiphilic molecules (gemini) in the presence of the mixture of chiral anionic nucleotides and nonchiral anions are investigated. We demonstrate that subtle balance of various physico‐chemical parameters and the competition between chiral and nonchiral anions at the interface of gemini assemblies influences the expression of molecular chirality at the micrometer scale through the hierarchical molecular assembly.

中文翻译:

通过手性核苷酸和非手性单阴离子之间的平衡,双子表面活性剂的层次手性表达聚集。

研究了在手性阴离子核苷酸和非手性阴离子的混合物存在下非手性双亲两性分子(双子座)的组装行为。我们证明了各种理化参数之间的微妙平衡以及双子组装体界面处的手性和非手性阴离子之间的竞争会影响分子级通过分子组装在微米尺度上的手性表达。
更新日期:2020-04-28
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