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Simulation of 3-D lithium dendritic evolution under multiple electrochemical states: A parallel phase field approach
Energy Storage Materials ( IF 20.4 ) Pub Date : 2020-05-05 , DOI: 10.1016/j.ensm.2020.04.011
Zhenliang Mu , Zhipeng Guo , Yuan-Hua Lin

The lithium battery is considered as one of the most reliable energy storage methods. The growth of dendrites is a primary challenge for the lithium battery. To simulate 3-D lithium dendrite evolution, a generic parallel computing library was implemented to solve nonlinear phase field governing equations to realize high computation efficiency. Lithium evolution under multiple electrochemical states, including charging, suspending and discharging is studied. Accordingly, growing, healing and necking of dendrites are observed. The driving force, ion concentration and the electric potential are investigated to understand the influence of surface tension and electrochemical reaction on behaviors of lithium. The source code of the program is available to promote the development of the phase field method in this field.



中文翻译:

多种电化学状态下3-D锂树枝状结晶的模拟:平行相场方法

锂电池被认为是最可靠的能量存储方法之一。树突的生长是锂电池的主要挑战。为了模拟3-D锂树枝状晶体的演化,使用通用并行计算库来求解非线性相场控制方程,以实现较高的计算效率。研究了多种电化学状态下锂的析出,包括充电,悬浮和放电。因此,观察到树突的生长,愈合和颈缩。研究了驱动力,离子浓度和电势,以了解表面张力和电化学反应对锂行为的影响。该程序的源代码可用于促进该领域中相场方法的发展。

更新日期:2020-05-05
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