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Polymer supported metallic nanoparticles as a solid catalyst for the removal of organic pollutants
Cellulose ( IF 5.7 ) Pub Date : 2020-05-04 , DOI: 10.1007/s10570-020-03193-8
Sher Bahadar Khan , Mohammad Sherjeel Javed Khan , Tahseen Kamal , Abdullah M. Asiri , Esraa M. Bakhsh

Nowadays, considerable attention has been gained for metal-based nanocatalysts due to their high catalytic activity. Herein, copper-cotton cellulose (Cu-CC) and metal nanoparticles supported on Cu-CC (MNPs@Cu-CC) were prepared. Zero-valent nanoparticles (NPs) of silver (Ag), and iron (Fe) were grown on Cu-CC and utilized as catalyst in few important organic reduction reactions. The prepared Cu-CC, Fe@Cu-CC and Ag@Cu-CC catalysts were utilized in catalytic reduction of nitrophenols and dyes for their evaluation. Among all the tested catalysts, Cu-CC efficiently reduced 4-nitrophenol (4-NP) and methyl orange dye (MO). The reduction rate constants of 4-NP and MO were 9.94 × 10−3 and 1.12 × 10−2 s–1, respectively. Further the catalytic activity of the more efficient Cu-CC was optimized by varying its amount, nitophenols and dyes, and NaBH4 concentrations. The stability, re-usability and loss in catalytic activity of the NPs were analyzed by the recyclability, in which the Cu-CC was utilized several times for the reduction of 4-NP and MO which suggest that the designed catalyst can be easily prepared, recovered simply by discarding the dye after completion of reaction, recyclable and have good catalytic activity.



中文翻译:

聚合物负载的金属纳米颗粒作为用于去除有机污染物的固体催化剂

如今,由于金属基纳米催化剂的高催化活性,引起了相当大的关注。在此,制备了铜棉纤维素(Cu-CC)和负载在Cu-CC上的金属纳米颗粒(MNPs @ Cu-CC)。银(Ag)和铁(Fe)的零价纳米颗粒(NPs)在Cu-CC上生长,并在少数重要的有机还原反应中用作催化剂。所制备的Cu-CC,Fe @ Cu-CC和Ag @ Cu-CC催化剂用于催化还原硝基酚和染料以进行评估。在所有测试的催化剂中,Cu-CC有效还原了4-硝基苯酚(4-NP)和甲基橙染料(MO)。4-NP和MO的还原速率常数分别为9.94×10 -3和1.12×10 -2  s –1, 分别。此外,更高效的Cu-CC的催化活性通过改变其含量,硝基酚和染料以及NaBH 4的浓度进行了优化。通过可回收性分析了NPs的稳定性,可重复使用性和催化活性的损失,其中多次使用Cu-CC还原了4-NP和MO,这表明所设计的催化剂易于制备,反应完成后,只需丢弃染料即可回收,可回收利用,并具有良好的催化活性。

更新日期:2020-05-04
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