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Soft-template and simple hydrothermal method to synthesize Fe-Co oxide on nickel foam and apply it to supercapacitors
Ionics ( IF 2.8 ) Pub Date : 2020-05-02 , DOI: 10.1007/s11581-020-03535-3
Chenyu Du , Enshan Han , Li Gao , Lina Li , Shunpan Qiao , Lamei Sun , Jiabao Liu

The exploration of high-performance supercapacitors (SCs) has attracted wide attention worldwide. Herein, iron cobalt oxide (FeCo2O4) nanocomposites were prepared by using soft-template and hydrothermal method. The prepared FeCo2O4 electrode material presented good dispersivity and had different flower-like structures and flocculent structures, which exhibited high capacitance and cyclic stability. Specially, the FeCo2O4 electrode with the usage of 0.5 g polyvinylpyrrolidone (PVP), sodium dodecyl sulfate (SDS), cetyltrimethylammonium bromide (CTAB), and none template agents showed high capacitance of 1231.1, 956.2, 1027.8, and 677.3 F g−1 at 1 A g−1. Furthermore, we used an optimized FeCo2O4 electrode material as the positive electrode, activated carbon (AC) as the negative electrode, and 6 M KOH solution as the electrolyte to assemble an asymmetric supercapacitor (ASC). The resulting ASC device exhibits a favorable energy density of 51.2 Wh kg−1 and a high power density of 775.4 W kg−1.

中文翻译:

用软模板和简单的水热法在泡沫镍上合成Fe-Co氧化物并将其应用于超级电容器

高性能超级电容器(SC)的探索已引起全世界的广泛关注。本文采用软模板法和水热法制备了钴酸铁(FeCo 2 O 4)纳米复合材料。制备的FeCo 2 O 4电极材料具有良好的分散性,并具有不同的花状结构和絮状结构,具有较高的电容量和循环稳定性。特别是,使用0.5 g聚乙烯吡咯烷酮(PVP),十二烷基硫酸钠(SDS),十六烷基三甲基溴化铵(CTAB)的FeCo 2 O 4电极,没有一种模板剂显示1231.1、956.2、1027.8和677.3 F g的高电容-1在1 A g-1。此外,我们使用优化的FeCo 2 O 4电极材料作为正电极,使用活性炭(AC)作为负电极,并使用6 M KOH溶液作为电解质来组装不对称超级电容器(ASC)。所得的ASC装置表现出51.2 Wh kg -1的有利能量密度和775.4 W kg -1的高功率密度。
更新日期:2020-05-02
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