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Radical addition-transfer of xanthates to 3,3,3-trifluoro-1-propene. A versatile and inexpensive access to trifluoromethyl substituted building blocks
Journal of Fluorine Chemistry ( IF 1.9 ) Pub Date : 2020-05-01 , DOI: 10.1016/j.jfluchem.2020.109538
Kenny Delacroix , Marc Perez , Laurent Petit

The controlled intermolecular addition of a series of xanthates to 3,3,3-trifluoro-1-propene represents a convenient, versatile, and inexpensive route to highly functional organofluorine derivatives. The initial radical adducts can be further transformed into original trifluoromethyl substituted building blocks and relevant chemical intermediates.



中文翻译:

黄药的自由基加成转移至3,3,3-三氟-1-丙烯。多用途且廉价的三氟甲基取代的结构单元

一系列黄原酸酯在3,3,3-三氟-1-丙烯中的受控分子间加成代表了方便,通用且廉价的制备高官能度有机氟衍生物的途径。初始的自由基加合物可以进一步转化为原始的三氟甲基取代的结构单元和相关的化学中间体。

更新日期:2020-05-01
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