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Enhanced Electromechanical Properties of 0.65Bi1.05FeO3–0.35BaTiO3 Ceramics through Optimizing Sintering Conditions
Physica Status Solidi (A) - Applications and Materials Science ( IF 2 ) Pub Date : 2020-03-20 , DOI: 10.1002/pssa.201900970
Tauseef Ahmed 1 , Salman Ali Khan 1 , Fazli Akram 1 , Jihee Bae 1 , Soo Yong Choi 1 , Ali Hussain 2 , Tae Kwon Song 1 , Yeon Soo Sung 3 , Myong-Ho Kim 1 , Soonil Lee 1
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Lead‐free piezoelectric 0.65Bi1.05FeO3–0.35BaTiO3 (BF–35BT) ceramics are synthesized via conventional solid‐state reaction by varying sintering dwell time (t s). The crystalline phase, microstructures, and piezoelectric properties of BF–35BT are evaluated at room temperature. BF–35BT ceramics with improved electrical properties in a narrow range of t s are obtained. Enhanced electromechanical properties are obtained in ceramics sintered at 1000 °C for 3 h. X‐ray diffraction reveals a single perovskite structure with pseudocubic symmetry. A prominent enhancement in remanent polarization (P r) and coercive field (E c) is obtained. Typical ferroelectric behaviors are obtained, whereas unipolar and bipolar strains are enhanced with increasing t s. The static piezoelectric constants (d 33) = 187 pC N−1, whereas dynamic piezoelectric constants (d *33) = 387 pm V−1 at a field of 5 kV mm−1 with Curie temperature (T C) = 422 °C.

中文翻译:

通过优化烧结条件增强了0.65Bi1.05FeO3-0.35BaTiO3陶瓷的机电性能

无铅压电0.65Bi 1.05 FeO 3 –0.35BaTiO 3(BF-35BT)陶瓷是通过改变烧结停留时间(t s)的常规固态反应合成。在室温下评估BF-35BT的结晶相,微结构和压电性能。获得了在较小的t s范围内具有改善的电性能的BF-35BT陶瓷。在1000°C烧结3 h的陶瓷中可获得增强的机电性能。X射线衍射显示具有伪立方对称性的单个钙钛矿结构。剩余极化强度(P r)和矫顽场(E c)。获得了典型的铁电行为,而单极性和双极性应变随t s的增加而增强。静态压电常数(d 33)= 187 pC N -1,而动态压电常数(d * 33)= 387 pm V -1在5 kV mm -1的场上,居里温度(T C)= 422°C 。
更新日期:2020-03-20
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