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Solvothermal synthesis of Fe 3 S 4 @graphene composite electrode materials for energy storage
Carbon Letters ( IF 4.5 ) Pub Date : 2020-04-07 , DOI: 10.1007/s42823-020-00139-9
Muthumalai Karuppasamy , Dinesh Muthu , Yuvaraj Haldorai , Ramasamy Thangavelu Rajendra Kumar

Necessity of novel energy storage devices extensively increased due to consumption of high power in various devices. To address the issues, in this report, we are addressing with a composite Iron Sulfide/reduced Graphene Oxide (Fe3S4/rGO) synthesized using the standard solvothermal method. X-ray diffraction and Field Emission Scanning Electron Microscope analysis results confirmed that Face-Centered cubic crystal structure of Fe3S4 and rGO’s surface is decorated with a mean diameter of < 50 nm Fe3S4 respectively. Transmission Electron Microscopy images show further evidence that dispersed Fe3S4 on the rGO surface. Fe3S4/rGO exhibits specific capacitance of 560 F/g than its individual counterparts (Fe3S4 = 200 F/g and rGO = 145 F/g) at 1 A/g of current density and maximum cyclic stability of 91% capacitance retention after 2000 cycles that may be the influence of synergy between the composite materials.



中文翻译:

溶剂热合成Fe 3 S 4石墨烯复合电极材料的储能

由于各种设备中的高功率消耗,新型能量存储设备的需求大大增加。为了解决这些问题,在本报告中,我们将解决使用标准溶剂热法合成的硫化铁/还原氧化石墨烯(Fe 3 S 4 / rGO)复合材料。X射线衍射和场发射扫描电子显微镜分析结果证实,Fe 3 S 4和rGO表面的面心立方晶体结构分别装饰有平均直径<50 nm Fe 3 S 4。透射电子显微镜图像显示进一步的证据表明,Fe 3 S 4分散在rGO表面。铁3 在电流密度为1 A / g时,S 4 / rGO的比电容为560 F / g(Fe 3 S 4 = 200 F / g,rGO = 145 F / g),最大循环稳定性为91%电容2000次循环后的保留率可能是复合材料之间协同作用的影响。

更新日期:2020-04-07
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