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High-speed shearing prepare Bi2Se3 dispersions and effect of size on photothermal conversion
Results in Physics ( IF 5.3 ) Pub Date : 2020-04-30 , DOI: 10.1016/j.rinp.2020.103139
Yanling Liu , Yaoyao Zhou , Zejia Zhao , Qiurui Zhang , Chenrui Zeng , Guozhi Jia

Bi2Se3, as an important photothermal conversion semiconductor material, has been widely studied to realize the heat energy application. The Bi2Se3 nanoparticles (NPs) dispersion is prepared by the combined technology of grinding and high-speed shearing. The different size distribution of Bi2Se3 has been selected by tuning centrifugal rates and mechanism is discussed in detail. The NPs dispersion with radius of 330 nm has the best photothermal conversion, which selected at centrifugal rates of 3000 rpm. The Steady-state temperature of NPs dispersions at centrifugal rates of 1000 rpm can reaches 41.4 °C under 1.6 W laser irradiation.These show that the quantum confinement effect and the localized surface plasmon resonances (LSPR) of Bi2Se3 NPs play crucial roles for excellent photothermal conversion, which are in good agreement with the numerically theoretical calculation investigated using the finite difference time domain (FDTD) method.



中文翻译:

高速剪切制备Bi 2 Se 3分散体及其尺寸对光热转化的影响

作为重要的光热转换半导体材料,Bi 2 Se 3已经被广泛研究以实现热能的应用。Bi 2 Se 3纳米颗粒(NPs)分散体是通过研磨和高速剪切的组合技术制备的。Bi 2 Se 3的不同尺寸分布通过调整离心率来选择和详细讨论机理。半径为330 nm的NPs分散体具有最佳的光热转化率,可以在3000 rpm的离心率下选择。在1.6 W激光辐照下,NPs分散体在1000 rpm的离心速度下的稳态温度可以达到41.4°C,这表明Bi 2 Se 3 NPs的量子约束效应和局部表面等离子体激元共振(LSPR)起着关键作用。具有出色的光热转换性能,这与使用时差有限域(FDTD)方法研究的数值理论计算非常吻合。

更新日期:2020-04-30
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