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Monoterpene indole alkaloids in Uncaria rhynchophlly (Miq.) Jacks chinensis and their chemotaxonomic significance
Biochemical Systematics and Ecology ( IF 1.6 ) Pub Date : 2020-08-01 , DOI: 10.1016/j.bse.2020.104057
Zhenshan Chen , Zhenhua Tian , Yaowen Zhang , Xue Feng , Yunlun Li , Haiqiang Jiang

Abstract From the Uncaria rhynchophlly (Miq.) Jacks, twelve monoterpene indole alkaloids, such as harman (1), strictosamide (2), vincosidelactam (3), cadambine (4), 3α-dihydrocadambine (5), 7-epi-javaniside (6), rhynchophylline (7), isorhynchophylline (8), hirsutine (9), vincosamide-6′-O-β-D-glucopyranoside (10), vincosamide-11-O-β-D-glucopyranoside (11) and 2′-O-[β-D-glucopyranosyl-(1 → 6)-β-D-glucopyranosyl]-11-hydroxyvincosamide (12) were isolated and identified. Structure elucidation of these compounds was performed on the basis of NMR spectroscopic data. Compounds 2, 5, 6, 10, 11 and 12 were obtained from this species for the first time. Chemotaxonomic significance of these compounds is described herein.

中文翻译:

钩藤中单萜吲哚生物碱及其化学分类学意义

摘要来自钩藤(Miq.) Jacks,12种单萜吲哚生物碱,如harman (1)、strictosamide (2)、vincosidelactam (3)、cadambine (4)、3α-dihydrocadambine (5)、7-epi-javaniside (6)、钩藤碱 (7)、异钩藤碱 (8)、毛皮 (9)、长春酰胺-6'-O-β-D-吡喃葡萄糖苷 (10)、长春花胺-11-O-β-D-吡喃葡萄糖苷 (11) 和2'-O-[β-D-吡喃葡萄糖基-(1 → 6)-β-D-吡喃葡萄糖基]-11-羟基长春酰胺 (12) 被分离和鉴定。这些化合物的结构解析是在核磁共振光谱数据的基础上进行的。化合物 2、5、6、10、11 和 12 为首次从该物种中分离得到。本文描述了这些化合物的化学分类学意义。
更新日期:2020-08-01
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