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Removal of hexavalent chromium from wastewater using supported liquid membrane: synthesis of chromium‐iron complex through electrochemical reaction
Water and Environment Journal ( IF 2 ) Pub Date : 2020-04-22 , DOI: 10.1111/wej.12576
Supriyo Kumar Mondal 1 , Prabirkumar Saha 1
Affiliation  

Treatment of wastewater containing hexavalent chromium is the issue in this research. Supported liquid membrane with in situ electrochemical reaction in stripping section helps to reduce hexavalent chromium to trivalent chromium by forming chromium‐iron complex. Iron plate acts as anode in stripping section. The chromium‐iron complex is an useful value added product that can be used for various purposes such as catalyst in water‐gas shift reaction. Aliquat 336 has been used as carrier for transport of hexavalent chromium. Various physico‐chemical parameters have been optimised to detect the condition of maximum transport and precipitation of chromium‐iron complex in stripping phase. The important physico‐chemical parameters such as strip phase concentration, strip phase pH and concentration of carrier (% v/v) in Liquid Membrane have been selected through response surface methodology to obtain optimum performance for %precipitation of chromium.

中文翻译:

使用支撑液膜去除废水中的六价铬:通过电化学反应合成铬铁络合物

这项研究的课题是处理含六价铬的废水。原位支撑液膜汽提段中的电化学反应可通过形成铬铁络合物将六价铬还原为三价铬。铁板在剥离区用作阳极。铬铁络合物是有用的增值产品,可用于多种目的,例如水煤气变换反应中的催化剂。Aliquat 336已被用作运输六价铬的载体。优化了各种理化参数,以检测汽提阶段铬铁络合物的最大迁移和沉淀条件。已通过响应表面方法选择了重要的理化参数,例如汽提相浓度,汽提相pH值和液体膜中的载体浓度(%v / v),以获得铬的%沉淀的最佳性能。
更新日期:2020-04-22
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