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Metal–organic frameworks of Cu 2 (TPTC)-catalyzed cascade C–S coupling/C sp2 –H hydroxylation reaction
Journal of the Iranian Chemical Society ( IF 2.4 ) Pub Date : 2020-01-28 , DOI: 10.1007/s13738-020-01860-y An-Qi Tian , Shan Liu , Zhi-Lin Ren , Long Wang , Dong-Sheng Li
中文翻译:
Cu 2(TPTC)催化的金属有机骨架级联C–S偶联/ C sp2 –H羟基化反应
更新日期:2020-01-28
Journal of the Iranian Chemical Society ( IF 2.4 ) Pub Date : 2020-01-28 , DOI: 10.1007/s13738-020-01860-y An-Qi Tian , Shan Liu , Zhi-Lin Ren , Long Wang , Dong-Sheng Li
Abstract
This paper reports a novel disulfide-directed Csp2–H hydroxylation cascade reaction strategy catalyzed by Cu2(TPTC), a metal–organic framework material with binuclear Cu(II) paddlewheel nodes. In the strategy, Cu2(TPTC) MOF can effectively catalyze the coupling reaction of disulfide and arylboronic acid, and realize the disulfide-directed Csp2–H hydroxylation reaction. This reaction proceeded well under Cu2(TPTC) MOF catalyst with good yields, which provides an efficient method to the synthesis of functional organic molecules, such as 2-(phenylthio)phenols derivatives.Graphic abstract
中文翻译:
Cu 2(TPTC)催化的金属有机骨架级联C–S偶联/ C sp2 –H羟基化反应