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Investigation of NH3 gas sensing behavior of intercalated PPy–GO–WO3 hybrid nanocomposite at room temperature
Materials Science and Engineering: B ( IF 3.6 ) Pub Date : 2020-04-29 , DOI: 10.1016/j.mseb.2020.114558
Heiner Albaris , Gurunathan Karuppasamy

Polypyrrole, Graphene oxide and WO3 nanostructures are synthesized by chemical polymerization, Modified Hummers method and hydrothermal method respectively. PPy–GO–WO3 hybrid nanocomposite is synthesized by the polymerization of polypyrrole in the presence of GO–WO3 nanocomposite. Band gap energy of the hybrid nanocomposite is calculated as 4.1 eV using UV–Visible absorption spectroscopy. Electrodes are fabricated by spin coating the sensing materials on a Printed Circuit Board. The electrodes have been investigated for their response towards Oxygen, Hydrogen, Ammonia and Liquid Petroleum Gas at room temperature. Among the different gases, electrodes are selectively sensitive to ammonia gas with improved sensitivity (58%), response time (50 s) and recovery time (120 s) in the presence of 10 ppm gas. The lower limit of detection of the electrode is observed as 5 ppm. The reproducibility of the response of the electrodes is tested and it is stable for the period of 50 days.



中文翻译:

室温下插层PPy–GO–WO 3杂化复合材料NH 3气敏行为的研究

分别通过化学聚合,改性悍马法和水热法合成了聚吡咯,氧化石墨烯和WO 3纳米结构。PPy–GO–WO 3杂化纳米复合材料是在GO–WO 3存在下通过聚吡咯聚合而合成的纳米复合材料。使用紫外可见吸收光谱法将杂化纳米复合材料的带隙能量计算为4.1 eV。通过在印刷电路板上旋涂感应材料来制造电极。研究了电极在室温下对氧气,氢气,氨气和液态石油气的响应。在不同的气体中,电极在10 ppm的气体存在下对氨气选择性敏感,灵敏度提高(58%),响应时间(50 s)和恢复时间(120 s)。观察到电极的检测下限为5ppm。测试了电极响应的可重复性,并在50天的时间内保持稳定。

更新日期:2020-04-29
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