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Synthesis of liquid hydrocarbons enriched with triptane via dimethyl ether conversion over combined catalyst
Russian Chemical Bulletin ( IF 1.7 ) Pub Date : 2020-04-01 , DOI: 10.1007/s11172-020-2819-2
Z. M. Matieva , Yu. M. Snatenkova , N. V. Kolesnichenko , I. M. Gerzeliev , A. L. Maximov

A combined catalytic system composed of catalysts with different functions was prepared. The catalyst for the synthesis of lower olefins based on is H-ZSM-5 zeolite modified with Mg, was mixed with the catalyst for alkylation of isobutane by olefins based on H-Y zeolite modified with La and Pd. In the presence of the combined system, liquid branched hydrocarbons were synthesized from dimethyl ether in a hydrogen medium at 340 °C and a pressure of 10 MPa. The effect of the composition of the combined catalyst on its selectivity to liquid hydrocarbons and, specifically, triptane was shown.

中文翻译:

复合催化剂上二甲醚转化合成富含曲烷烃的液态烃

制备了由不同功能的催化剂组成的复合催化体系。以Mg改性H-ZSM-5沸石为基础合成低级烯烃的催化剂,与以La和Pd改性HY沸石为基础的烯烃烷基化异丁烷催化剂混合。在组合系统存在下,在氢气介质中,在 340 °C 和 10 MPa 的压力下,由二甲醚合成液态支链烃。显示了组合催化剂的组成对其对液态烃,特别是曲烷的选择性的影响。
更新日期:2020-04-01
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