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Electrochemical Reduction of α‐Amino Allenylphosphonates to α‐Amino Allylphosphonates
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2020-04-27 , DOI: 10.1002/ejoc.202000534
Pauline Adler 1 , Pedro de Oliveira 2 , Nicolas Rabasso 1
Affiliation  

Table of content text: The selective reduction of allenyl to allylphosphonates was achieved using an efficient electrochemical method. The reduction products are obtained in moderate to good yields. Moreover, in the case of tosylamine compounds, the unprotected amino‐allylphosphonates were accessed through a simultaneous reduction and cleavage of the tosyl group from the nitrogen atom. The mechanism of this reduction is also discussed.
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中文翻译:

将α-氨基烯丙基膦酸酯电化学还原为α-氨基烯丙基膦酸酯

目录文本:使用有效的电化学方法将烯基选择性还原为烯丙基膦酸酯。还原产物以中等至良好的产率获得。此外,对于甲苯磺胺化合物,未保护的氨基烯丙基膦酸酯可通过同时还原和裂解氮原子上的甲苯磺酰基来获得。还讨论了这种减少的机制。
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更新日期:2020-07-01
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