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Study on acrylate peelable nuclear detergent for film formation at low temperature.
Applied Radiation and Isotopes ( IF 1.6 ) Pub Date : 2020-04-26 , DOI: 10.1016/j.apradiso.2020.109187
Kun Zhang 1 , Shanqiang Wang 2 , Zeyin He 3 , Meixiao Wu 4 , Xingwei Cao 5
Affiliation  

The human handling of radioactive contamination on the surface of nuclear facilities has become an important issue in the development of nuclear industry. In order to solve the poor film-forming of nuclear detergent in low temperature, a new type low temperature film-forming peelable nuclear decontaminant was proposed. The acrylate copolymers were developed by solution polymerization of acrylic monomers in the mass ratio of BA (butyl acrylate): MMA (methyl methacrylate): AA (acrylic acid): EA (ethyl acetate) is equal to 50:45:5:100 considering different proportioning methods and reaction temperature. Then the orthogonal test was carried out to study the effects of crosslinker, plasticizer, thickener, release agent on the decontamination performance based on the orthogonal test method, and the optimal peelable formula of peelable nuclear detergent was obtained. Next the infrared properties, glass transition temperature, molecular weight of polymer and decontamination efficiency of peelable nuclear decontaminant were studied by experiments. The results show that the proposed low-temperature film-forming peelable radioactive decontamination agent can form film on concrete, sand, terrazzo, stainless steel and other surfaces, and is easy to peel off. The decontamination rate of this material is more than 82%.



中文翻译:

用于低温成膜的丙烯酸酯可剥离核清洁剂的研究。

人工处理核设施表面的放射性污染已成为核工业发展中的重要问题。为了解决核清洁剂在低温下成膜不良的问题,提出了一种新型的低温成膜可剥离核净化剂。考虑到BA(丙烯酸丁酯):MMA(甲基丙烯酸甲酯):AA(丙烯酸):EA(乙酸乙酯)的质量比等于50:45:5:100,通过丙烯酸单体的溶液聚合来开发丙烯酸酯共聚物不同的配比方法和反应温度。然后采用正交试验方法,通过正交试验研究了交联剂,增塑剂,增稠剂,脱模剂对去污性能的影响,得到了可剥离核清洁剂的最佳可剥离配方。接下来,通过实验研究了红外性能,玻璃化转变温度,聚合物的分子量和可剥离核净化剂的净化效率。结果表明,所提出的低温成膜性可剥离放射性去污剂可以在混凝土,沙子,水磨石,不锈钢等表面上形成膜,并且易于剥离。该材料的去污率超过82%。沙,水磨石,不锈钢等表面,并且容易剥离。该材料的去污率超过82%。沙,水磨石,不锈钢等表面,并且容易剥离。该材料的去污率超过82%。

更新日期:2020-04-26
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