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The evolution of microstructure and thermal conductivity of mesophase pitch-based carbon fibers with heat treatment temperature
New Carbon Materials ( IF 5.7 ) Pub Date : 2019-03-13 , DOI: 10.1016/s1872-5805(19)60002-8
Zhen Fan , Min Cao , Wen-bing Yang , Shi-peng Zhu , Zhi-hai Feng

The evolution of microstructure and morphology of mesophase pitch-based carbon fibers (MPCFs) with heat treatment temperature (HTT) was investigated by SEM, TEM, Raman spectroscopy and XRD. The thermal conductivity of the MPCFs was examined by a modified 3 ω method. Results indicate that the degree of graphitization and the thermal conductivity of the MPCFs increase with HTT. The thermal conductivity of the MPCFs reaches 518 W/m·K at a HTT of 3000 °C. The thermal conductivity of MPCFs varies linearly with HTT in two distinct ranges, 1 000-2 000 and 2 300-3 000 °C, that respectively correspond to the growth and orientation of graphite crystallites.



中文翻译:

中间相沥青基碳纤维的微观结构和导热系数随热处理温度的变化

通过SEM,TEM,拉曼光谱和XRD研究了中间相沥青基碳纤维(MPCFs)随着热处理温度(HTT)的微观结构和形貌的演变。通过改进的3ω方法检查了MPCF的导热系数。结果表明,MPTTs的石墨化程度和导热系数随HTT的增加而增加。在3000°C的高温下,MPCF的导热系数达到518 W / m·K。MPCF的热导率随HTT在两个不同的范围内线性变化,分别为1 000-2 000和2 300-3 000°C,分别对应于石墨微晶的生长和取向。

更新日期:2019-03-13
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