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3D nanoweb-like zeolitic imidazole framework in a microfluidic system for catalytic applications
Reaction Chemistry & Engineering ( IF 3.9 ) Pub Date : 2020-04-24 , DOI: 10.1039/d0re00004c
Dong-Hyeon Ko 1, 2, 3, 4, 5 , Rui Chen 5, 6, 7, 8 , Dengrong Sun 1, 2, 3, 4, 5 , Jin Woo Leem 5, 7, 8, 9 , Jeong-Un Joo 1, 2, 3, 4, 5 , Il-Suk Kang 5, 10, 11, 12 , Myung Mo Sung 5, 7, 8, 9 , Haiwon Lee 5, 6, 7, 8, 9 , Dong-Pyo Kim 1, 2, 3, 4, 5
Affiliation  

A 3D nanoweb-like zeolite imidazole framework (ZIF-8) as an efficient heterogeneous catalyst was structured inside a functionalized microfluidic channel by immobilizing the ZIF on 3D carbon nanotube (CNT) networks across the gap among the built-in micropillars for the Knoevenagel condensation reaction. The quantitative conversion was achieved under mild conditions of ethanol solvent and room temperature. The ZIF-8 3D nanoweb systems showed higher conversion than the identical systems without CNT-based networks which indicates the catalytic superiority of 3D nanoweb structures.

中文翻译:

3D纳米网状沸石咪唑骨架在微流体系统中的催化应用

通过将ZIF固定在3D碳纳米管(CNT)网络上跨越内置微柱之间的缝隙进行Knoevenagel缩合的3D纳米网状沸石咪唑骨架(ZIF-8)作为有效的非均相催化剂反应。在温和的乙醇溶剂和室温条件下实现了定量转化。与没有基于CNT的网络的相同系统相比,ZIF-8 3D纳米纤维网系统显示出更高的转化率,这表明3D纳米纤维网结构具有催化优势。
更新日期:2020-04-24
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