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De-stabilization of charge-order state through in-homogeneity in random ionic distribution in the particles of polycrystalline $$\hbox {Eu}_{0.2}\hbox {La}_{0.3}\hbox {Sr}_{0.2}\hbox {Ca}_{0.3}\hbox {MnO}_{3}$$Eu0.2La0.3Sr0.2Ca0.3MnO3 sample
Bulletin of Materials Science ( IF 1.8 ) Pub Date : 2020-04-23 , DOI: 10.1007/s12034-019-2033-8
K De , P Dhak , S De , P Dutta , K Dey , S Mukherjee , S Chatterjee , S Das

In this study the perovskite manganite \(\hbox {Eu}_{0.2}\hbox {La}_{0.3}\hbox {Sr}_{0.2}\hbox {Ca}_{0.3}\hbox {MnO}_{3}\) batch integrated sample is studied, with special modification done to introduce localized structural strain without micro-level (grains) modification. This consequence successfully generates opposite nature of high orthorhombic strain along b-axis in these samples, although the general structure is same for both with Pnma space group. The sharp magnetic transitions (both Curie temperature and charge-order transition) are reported to be mixed in presence of random ionic distribution in its structure. The diffused insulator-metal behaviour, de-stabilization of magnetic state and phase transitions associated with inherent anisotropic strain is discussed and is explained based on chemical disorder-induced structural strain in the present system.



中文翻译:

通过多晶$$ \ hbox {Eu} _ {0.2} \ hbox {La} _ {0.3} \ hbox {Sr} _ {{0.2}}中的随机离子分布中的不均匀性,使电荷有序态不稳定\ hbox {Ca} _ {0.3} \ hbox {MnO} _ {3} $$ Eu0.2La0.3Sr0.2Ca0.3MnO3样本

在本研究中,钙钛矿锰矿\(\ hbox {Eu} _ {0.2} \ hbox {La} _ {0.3} \ hbox {Sr} _ {0.2} \ hbox {Ca} _ {0.3} \ hbox {MnO} _研究了{3} \)批处理的集成样本,并进行了特殊修改,以引入局部结构应变,而没有进行微级(晶粒)修改。这些结果成功地在这些样品中产生了沿b轴的正交斜应变的相反性质,尽管Pnma的总体结构相同空间群。据报道,尖锐的磁跃迁(居里温度和电荷阶跃跃迁)在其结构中存在随机的离子分布时混合在一起。讨论了绝缘子-金属的扩散行为,磁态的不稳定以及与固有各向异性应变相关的相变,并在本系统中基于化学无序引起的结构应变进行了解释。

更新日期:2020-04-23
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