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WO3 thin films doped with Ru by facile chemical method with enhanced electrochromic properties for electrochromic window application
Materials Science and Engineering: B ( IF 3.6 ) Pub Date : 2020-04-20 , DOI: 10.1016/j.mseb.2020.114542
Suvarna R. Bathe , P.S. Patil

We report on WO3 thin films observed as platelets doped with Ruthenium (Ru) in various doping concentrations and synthesized using a facile surfactant free acid precipitation method. The synthesized thin films annealed at 500 °C for an hourrevealedchanges in morphology from plate-like structure to agglomerated nanoparticles after doping of Ru (0.05 and 0.1 wt%) in WO3. The resulting Ru doped WO3 thin films reveals two times improved performance in cycle stability and diffusion coefficient is increased by ten times as compared to synthesized pristine WO3thin films and these are discussed in terms of Ru doping effect in host matrix which induced compositional inhomogeneity, morphological change and disorder to show a fast switching response (coloration time; Tc = 2.28 s and beaching time; Tb = 1.98 s) and high reversibility 87% with coloration efficiency of 67 cm2/C and retention after 1000 cycles.



中文翻译:

易化学方法掺杂Ru的WO 3薄膜,具有增强的电致变色性能,适用于电致变色窗应用

我们报告了观察到的WO 3薄膜,这些血小板是在各种掺杂浓度下掺有钌(Ru)的血小板,并使用一种简便的表面活性剂游离酸沉淀法合成。在WO 3中掺入Ru(0.05和0.1 wt%)后,合成的薄膜在500°C的温度下退火一个小时,从板状结构到团聚的纳米颗粒的形貌变化得以揭示。与合成的原始WO 3相比,所得的Ru掺杂的WO 3薄膜在循环稳定性方面的性能提高了两倍,扩散系数提高了十倍。讨论了这些薄膜,并根据基质中Ru的掺杂作用对这些薄膜进行了讨论,这些基质诱导成分不均匀,形态变化和无序,表现出快速的开关响应(着色时间; T c  = 2.28 s和海滩时间; T b  = 1.98 s),并且高可逆性87%,着色效率为67 cm 2 / C,1000次循环后仍保留。

更新日期:2020-04-20
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