Abstract Rotational spectra of benzene-water and several related complexes were fit according to a free internal rotor model over the last three decades, though the model did not explain all of the excited state transitions found or yield an RMS deviation within experimental uncertainty. We use a model Hamiltonian, including Coriolis interactions that is able to explain all excited state transitions observed, giving a fit with an RMS deviation within experimental uncertainty.

中文翻译：

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苯-水和相关分子复合物中的科里奥利相互作用

摘要 根据过去 30 年间的自由内转子模型拟合苯-水和几种相关配合物的旋转光谱，尽管该模型并未解释所有发现的激发态跃迁或在实验不确定性范围内产生 RMS 偏差。我们使用模型哈密顿量，包括能够解释观察到的所有激发态跃迁的科里奥利相互作用，在实验不确定性内给出与 RMS 偏差的拟合。