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High-Power Aqueous Zn-H2O2 Batteries for Multiple Applications
Cell Reports Physical Science ( IF 8.9 ) Pub Date : 2020-03-25 , DOI: 10.1016/j.xcrp.2020.100027
Lingsong Xu , Jiehua Liu , Peng Chen , Zhuangzhuang Wang , Dejian Tang , Xiaosong Liu , Fancheng Meng , Xiangfeng Wei

Metal-air batteries have high capacities and power densities, but performance is limited in the absence of oxygen. Hydrogen peroxide not only has oxygen storage capacity of ∼1,600 times that of air but is also in some ways more convenient for storage and transportation than high-pressure cylinders. H2O2 may be a viable alternative in non-oxygen conditions. Here, we report aqueous Zn-H2O2 battery that is designed by replacing O2 gas with hydrogen peroxide using Co/N doped carbon nanosheet as a multifunctional catalyst for oxygen reduction reaction, oxygen evolution reaction, and H2O2 decomposition. The optimized Zn-H2O2 battery exhibits superior high-rate discharging performance among 20–120 mA cm−2, 23% higher than that of Zn-air battery at the rate of 120 mA cm−2. As an application, two-serial Zn-H2O2 batteries can light a red LED array and work well in water. Therefore, we think Zn-H2O2 battery has numerous applications in high-power devices.



中文翻译:

多种应用的大功率Zn-H 2 O 2水性电池

金属空气电池具有高容量和功率密度,但是在没有氧气的情况下性能受到限制。过氧化氢不仅具有约1600倍于空气的氧气存储能力,而且在某些方面还比高压钢瓶更便于存储和运输。H 2 O 2在无氧条件下可能是可行的选择。在这里,我们报道了Zn-H 2 O 2水性电池,该电池是通过使用Co / N掺杂的碳纳米片作为氧还原反应,氧释放反应和H 2 O 2分解的多功能催化剂用过氧化氢代替O 2气体而设计的。优化的Zn-H 2 O 2电池在20–120 mA cm -2之间表现出优异的高倍率放电性能,在120 mA cm -2的情况下比锌空气电池高23%。作为应用,两节Zn-H 2 O 2电池可点亮红色LED阵列,并在水中良好工作。因此,我们认为Zn-H 2 O 2电池在大功率设备中具有广泛的应用。

更新日期:2020-04-20
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