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Zeolites in the synthesis of quinolines by the Skraup reaction
Russian Chemical Bulletin ( IF 1.7 ) Pub Date : 2020-03-01 , DOI: 10.1007/s11172-020-2793-8 N. G. Grigor´eva , A. V. Bayburtli , R. Z. Kuvatova , T. V. Semenova , S. V. Bubennov , G. Z. Raskildina , S. S. Zlotsky , B. I. Kutepov
Russian Chemical Bulletin ( IF 1.7 ) Pub Date : 2020-03-01 , DOI: 10.1007/s11172-020-2793-8 N. G. Grigor´eva , A. V. Bayburtli , R. Z. Kuvatova , T. V. Semenova , S. V. Bubennov , G. Z. Raskildina , S. S. Zlotsky , B. I. Kutepov
A novel heterogeneous catalytic method for the synthesis of quinoline ( 1) and a mixture of 2- and 4-methylquinolines ( 2) by Skraup reaction in the presence of H-Y, H-MOR, H-Beta, H-ZSM-5 zeolite catalysts has been proposed. H-Beta and H-ZSM-5 zeolite catalysts demonstrated the highest activity, selectivity and stability: the total selectivity to 1 and 2 was up to 74% with a dominance of quinoline in the fraction, the conversion of aniline was 88–100%.
中文翻译：
通过 Skraup 反应合成喹啉的沸石
在HY、H-MOR、H-Beta、H-ZSM-5沸石催化剂存在下通过Skraup反应合成喹啉(1)和2-和4-甲基喹啉(2)混合物的一种新型多相催化方法已提出。H-Beta 和 H-ZSM-5 沸石催化剂表现出最高的活性、选择性和稳定性：对 1 和 2 的总选择性高达 74%，其中喹啉占主导地位，苯胺转化率为 88-100% .
更新日期：2020-03-01
中文翻译：
通过 Skraup 反应合成喹啉的沸石
在HY、H-MOR、H-Beta、H-ZSM-5沸石催化剂存在下通过Skraup反应合成喹啉(1)和2-和4-甲基喹啉(2)混合物的一种新型多相催化方法已提出。H-Beta 和 H-ZSM-5 沸石催化剂表现出最高的活性、选择性和稳定性：对 1 和 2 的总选择性高达 74%，其中喹啉占主导地位，苯胺转化率为 88-100% .
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