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Fabrication of MgO@AC porous composite for CO 2 capture by a solid-state heat dispersion approach
Journal of Porous Materials ( IF 2.6 ) Pub Date : 2020-04-08 , DOI: 10.1007/s10934-020-00881-5
Guanghui Chen , Fei Wang , Shougui Wang , Weiwen Wang , Jipeng Dong , Fei Gao

Activated carbon (AC) supported MgO (MgO@AC) for CO2 capture has been facilely prepared with Mg(NO3)2 as precursor by a solid-state heat dispersion method. The prepared MgO@AC adsorbents with different magnesium loadings were characterized by X-ray diffraction (XRD), N2 adsorption/desorption and scanning electron microscope (SEM), and were investigated for the CO2 adsorption capacity, CO2 adsorption selectivity and cyclic stability. The characterization results reveal that the precursor of Mg(NO3)2 can be highly dispersed on the surfaces of the AC support and converted to MgO during the activation process at high temperatures. The experimental results show that the MgO@AC adsorbent with the MgO loadings of 5 mmol/g AC support achieves a high CO2 adsorption capacity, high CO2/N2 adsorption selectivity and excellent reversibility. Its good adsorption performance and facile fabrication process make it a promising adsorbent for CO2 capture from flue gases. In addition, the isosteric heat of CO2 adsorption on this adsorbent was calculated from the CO2 adsorption equilibrium isotherms at different temperatures using the Clausius–Clapeyron equation, the values are in the range of 45.4–20.1 kJ/mol.



中文翻译:

固态热分散法制备用于CO 2捕集的MgO @ AC多孔复合材料

活性炭(AC)支持的MgO(氧化镁@ AC)用于CO 2捕获已用Mg(NO被轻便制备32作为由固态热分散方法的前体。通过X射线衍射(XRD),N 2吸附/脱附和扫描电子显微镜(SEM)对所制备的不同镁含量的MgO @ AC吸附剂进行表征,并研究了其对CO 2的吸附能力,CO 2的吸附选择性和循环性。稳定性。表征结果表明,Mg(NO 32的前驱体可以高度分散在AC载体的表面上,并在高温活化过程中转化为MgO。实验结果表明,MgO负载量为5 mmol / g AC载体时,MgO @ AC吸附剂具有较高的CO 2吸附容量,高的CO 2 / N 2吸附选择性和优异的可逆性。其良好的吸附性能和便捷的制造工艺使其成为从烟气中捕获CO 2的有前途的吸附剂。此外,CO的等量吸附热2吸附在该吸附剂从CO计算出2 使用Clausius–Clapeyron方程在不同温度下的吸附平衡等温线,其值在45.4–20.1 kJ / mol的范围内。

更新日期:2020-04-21
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