ABSTRACT We report here the facile synthesis of a new series of hydroxy-thioxo-imidazole carboxylates in good yields using the cyanomethyl anion as an electrogenerated base which is formed when dry acetonitrile is electrolyzed at constant current, followed by addition of different thioureas and diazirine-3,3-dicarboxylate. The mechanism of the reaction, NMR shifts and IR are discussed and compared to density functional theory calculations. GRAPHICAL ABSTRACT

中文翻译：

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羟基-硫代-咪唑羧酸盐的电化学合成：实验和理论研究

摘要我们在此报告了使用氰甲基阴离子作为电生碱以良好的收率轻松合成了一系列新的羟基-硫代-咪唑羧酸盐，该碱是在恒定电流下电解干燥乙腈时形成的，然后加入不同的硫脲和二氮嗪- 3,3-二羧酸盐。讨论了反应机理、NMR 位移和 IR，并与密度泛函理论计算进行了比较。图形概要