Abstract

A little attempt has been made to get in touch with the green chemistry studying the successful occurrence of oxidation of 4-chlorobenzyl alcohol to 4-chlorobenzaldehyde in micellar media by Cr(VI), and its kinetics has been recorded spectrophotometrically following pseudo-first-order reaction conditions at λ_max = 440 nm. In this purpose, some common hetero-aromatic bases like 2-picolinic acid, 1,10-phenanthroline and 2,2′-bipyridine have been utilized successfully for many fold rate enhancement of the reaction. Necessary spectroscopic evidences have been produced in support of the product formation.

Graphic abstract

中文翻译：

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胶束介质中Cr（VI）杂芳族N碱促进4-氯苄醇的氧化

摘要

已进行了一些尝试，与绿色化学接触，研究了Cr（VI）在胶束介质中成功地将4-氯苄醇氧化为4-氯苯甲醛的过程，并通过伪第一-分光光度法记录了其动力学。为了反应条件中的λ_最大 = 440纳米。为此，已成功地利用一些常见的杂芳族碱，例如2-吡啶甲酸，1,10-菲咯啉和2,2'-联吡啶来提高反应的倍率。已经产生了必要的光谱学证据以支持产物形成。

图形摘要