Abstract The purpose of this study was to explore the molecular spectroscopic behaviors of the beta-arbutin on the toxic aldehyde of trans-crotonaldehyde in anti-skin cancer. Results revealed that both hydroxymethyl and phenolic hydroxyl of beta-arbutin led to the shift of the maximum ultraviolet peak of trans-crotonaldehyde from a very significant absorption peak at 300 nm to a very weak absorption peak at 310 nm and the significant shift of the aldehyde Raman band at 1689/cm of the toxic trans-crotonaldehyde in mitochondria and aldehyde dehydrogenase, respectively. The beta-arbutin acting on the toxic trans-crotonaldehyde highlighted the potential of anti-skin cancer and provided a valuable clue for the new application of the beta-arbutin.

中文翻译：

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β-熊果苷抗皮肤癌的分子光谱行为

摘要 本研究旨在探讨β-熊果苷对反式巴豆醛中毒性醛类抗皮肤癌作用的分子光谱行为。结果表明，β-熊果苷的羟甲基和酚羟基均导致反式巴豆醛的最大紫外峰从 300 nm 处非常显着的吸收峰移至 310 nm 处非常弱的吸收峰，并且醛的显着位移线粒体中毒性反式巴豆醛和醛脱氢酶的拉曼谱带分别为 1689/cm。作用于有毒反式巴豆醛的β-熊果苷突显了抗皮肤癌的潜力，并为β-熊果苷的新应用提供了有价值的线索。