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Copper-catalyzed O-alkenylation of phosphonates
Beilstein Journal of Organic Chemistry ( IF 2.7 ) Pub Date : 2020-04-03 , DOI: 10.3762/bjoc.16.56
Nuria Vázquez-Galiñanes , Mariña Andón-Rodríguez , Patricia Gómez-Roibás , Martín Fañanás-Mastral

Copper catalysis allows the direct oxygen alkenylation of dialkyl phosphonates with alkenyl(aryl)iodonium salts with selective transfer of the alkenyl group. This novel methodology proceeds with a wide range of phosphonates under mild conditions and gives straightforward access to valuable enol phosphonates in very good yields.

中文翻译:

铜催化膦酸酯的O-烯基化

铜催化作用允许二烷基膦酸酯与烯基(芳基)碘鎓盐直接进行氧烯基化,并选择性地转移烯基。这种新颖的方法可以在温和的条件下使用多种膦酸酯,并以非常高的收率直接获得有价值的烯醇膦酸酯。
更新日期:2020-04-03
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