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A stable nanoscaled Zr-MOF for the detection of toxic mycotoxin through a pH-modulated ratiometric luminescent switch.
Chemical Communications ( IF 4.9 ) Pub Date : 2020-05-19 , DOI: 10.1039/d0cc01006e
Xiaolei Guo 1 , Nansong Zhu 1 , Yue Lou 1 , Siyuan Ren 1 , Shirui Pang 1 , Yiqiang He 1 , Xiao-Bo Chen 2 , Zhan Shi 1 , Shouhua Feng 1
Affiliation  

A stable nanoscaled single-excitation ratiometric luminescent pH sensor (MPDB-PCN) over a broad pH range from 2.5 to 8.6 is fabricated through post-synthetic modification of PCN-224 with naphthalimide-derived molecules. Due to the rapid, sensitive and linear response to pH, MPDB-PCN is capable of detecting 3-nitropropionic acid (3-NPA), an acid neurotoxin in food safety, with a low detection limit of 15 μM in sugarcane juice.

中文翻译:

一种稳定的纳米级Zr-MOF,用于通过pH调节的比例发光开关检测有毒的霉菌毒素。

通过用萘二甲酰亚胺衍生的分子对PCN-224进行后合成修饰,制得了稳定的纳米级单激发比例发光荧光pH传感器(MPDB-PCN),pH范围从2.5到8.6。由于对pH值具有快速,灵敏和线性的响应,因此MPDB-PCN能够检测3-硝基丙酸(3-NPA)(食品安全中的酸性神经毒素),对甘蔗汁的检测限仅为15μM。
更新日期:2020-04-01
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