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Iron-Catalyzed Synthesis, Structure, and Photophysical Properties of Tetraarylnaphthidines
Molecules ( IF 4.6 ) Pub Date : 2020-04-01 , DOI: 10.3390/molecules25071608
Alexander Purtsas 1 , Sergej Stipurin 1 , Olga Kataeva 2 , Hans-Joachim Knölker 1
Affiliation  

We describe the synthesis and photophysical properties of tetraarylnaphthidines. Our synthetic approach is based on an iron-catalyzed oxidative C–C coupling reaction as the key step using a hexadecafluorinated iron–phthalocyanine complex as a catalyst and air as the sole oxidant. The N,N,N’,N’-tetraarylnaphthidines proved to be highly fluorescent with quantum yields of up to 68%.

中文翻译:

四芳基萘啶的铁催化合成、结构和光物理性质

我们描述了四芳基萘啶的合成和光物理特性。我们的合成方法基于铁催化的氧化 C-C 偶联反应作为关键步骤,使用十六氟化铁 - 酞菁配合物作为催化剂,空气作为唯一氧化剂。N,N,N',N'-四芳基萘烷被证明具有高荧光性,量子产率高达 68%。
更新日期:2020-04-01
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